Again, these secretions are poisonous, which means they are absorbed - assuming it doesn't bite you, you could pet a king cobra or other venomous snake all day with no ill effect, as those toxins need to be injected.
It's the absorbent nature of amphibian venom which has, among other things, given rise to the trend to licking certain species of toad to get high off of their toxins.
These poisons aren't just a potential safety concern for keepers and predators. They can also pose a threat to exhibit-mates. Some amphibians can be a challenge to house in mixed-species exhibits, as they may, say, soak in a water bowl and secrete their poison, to the deleterious effect of other species in their enclosure.
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